Stepwise Reduction and In Situ Loading of Core‐Shelled Pt@Cu Nanocrystals on TiO ₂ –NTs for Highly Active Hydrogen Evolution

In situ hydrogen loading on zirconium powder

For the first time, various hydride phases in a zirconium-hydrogen system have been prepared in a high-energy synchrotron X-ray radiation beamline and their transformation behaviour has been studied in situ. First, the formation and dissolution of hydrides in commercially pure zirconium powder were monitored in real time during hydrogenation and dehydrogenation, then whole pattern crystal struc...

In situ activation of a Ni catalyst with Mo ion for hydrogen evolution reaction in alkaline solution

In this study Ni catalyst have been activated during hydrogen evolution reaction (HER) by adding Mo ions into the alkaline electrolyte. After dissolving different amounts of ammonium molybdate in the 1M NaOH as electrolyte, Ni catalyst was used as cathode for HER. Afterwards a comparison between hydrogen overpotential measured in Ni catalyst with and without in situ activation has been made; th...

synthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate

در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...

Nanocomposite of MoS2 on ordered mesoporous carbon nanospheres: A highly active catalyst for electrochemical hydrogen evolution

MoS2 Formed on Mesoporous Graphene as a Highly Active Catalyst for Hydrogen Evolution

A highly active and stable electrocatalyst for hydrogen evolution is developed based on the in situ formation of MoS 2 nanoparticles on mesoporous graphene foams (MoS 2 /MGF). Taking advantage of its high specifi c surface area and its interconnected conductive graphene skeleton, MGF provides a favorable microenvironment for the growth of highly dispersed MoS 2 nanoparticles while allowing rapi...